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Gil Kalai
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To make this question and the various examples a more useful source this is a designated answer to point out connections between the various examples we collected. please indicate only strong, definite, nontrivial, and clear connections.

  1. The Petersen graph is obtained by identifying antipodal vertices and edges in the graph of the dodecahedron - one of the five platonic solids. Such an identification gives a polyhedral complex realizing the real projective plane. Applying this operation to the icosahedron leads to a 6-vertex triangulation of the real projective plane.