Let $\theta= \arcsin(1/4)/\pi$$\theta= \arcsin(1/4)$. Assume $\theta$ is a rational multiple of $\pi$.
Then, there exists some $n$ such that $\sin(n\theta)=0$. This gives $\cos(n \theta)= \pm 1$.
Set $z=\cos(\theta)+i \sin(\theta)$, then $z^n= \pm 1$ and $\frac{1}{z^n}=\pm 1$.
This gives that $z$ and $\frac{1}{z}$ are algebraic integers, and hence so is $$2 i\sin(\theta)=z- \frac{1}{z}$$
Therefore, $\frac{i}{2}$ is an algebraic integer, which is a contradiction.