Let me record the answer from the comments here.
Suppose $(W,S)$ is a finite Coxeter system, with associated root system $\Phi$ in Euclidean vector space $V$. (I don't think the assumption of crystallography is needed in anything I'm about to say, but if you care specifically about Type D, that is a crystallographic type so things will be even better there.)
The Coxeter arrangement associated to $\Phi$ is the central hyperplane arrangement with hyperplanes orthogonal to the roots. As mentioned in the question, theThe Coxeter complex $\Sigma$ of $W$ can be realized asby instersecting the order complexCoxeter arrangement with a small sphere around the origin, so the chambers of the latticehyperplane arrangement become the facets of intersectionsthe complex, the rays of the Coxeter arrangement become the vertices of $\Phi$the complex, and so on. This is a flag simplicial complex, homeomorphic to a sphere. ItsNote in particular that its facets correspond to the elements of $W$. A nice reference for this construction is Section 11.6 of T. Kyle Petersen's "Eulerian Numbers" textbook.
EDIT ADDED MUCH LATER: Sorry, As mentioned by the previous paragraph was wrong; in particularquestion-asker, in Types A and B the Coxeter complexarrangement is not always an order complex of a poset. The Coxeter complex: in Type A it is obtained from the Coxeter arrangement by intersectingorder complex of the arrangement withBoolean lattice, a sphere. It is truek.a. face lattice of the simplex; in Types A andType B we use the face lattice of the hypercube instead. But it is not always the case that the Coxeter arrangementcomplex is an order complex of a poset (in Type A that poset is the Boolean lattice, as was mentioned by the question-asker), but e.g. For instance, in Type D this is not the case. In fact, I believe the Coxeter complex is not thean order complex of anya poset exactly when the Coxeter diagram of $\Phi$ has no "forks" (i. Ite., is truea path, when ignoring edge decorations). These are exactly the Coxeter diagrams that correspond to regular polytopes and then I believe the Coxeter complex is always a flag simplicialwill be the order complex of the face lattice of the corresponding regular polytope.
The notion of Coxeter complex applies to infinite Coxeter groups as well, but I will not explain this; see Wikipedia.
For finite ("spherical") Coxeter groups, the Coxeter complex as mentioned is homeomorphic to a sphere; but even better, it is polytopal. The permutohedron of $W$ (sometimes called "Coxterhedron" in earlier references) is the convex hull of the $W$ orbit of any point in $V$ not on any hyperplane in the Coxeter arrangement. Its combinatorial structure does not depend on which point in the fundamental chamber we choose. The $W$-permutohedron is a simple polytope, and its vertices are in bijection with the elements of $W$.
In fact, there is another way to realize the $W$-permutohedron as a zonotope: it is the Minkowksi sum $\sum_{\alpha \in \Phi^+}[-\alpha/2,\alpha/2]$ (here the notation $[-\alpha/2,\alpha/2]$ means the line segment joining $-\alpha/2$ to $\alpha/2$; you can just think of this as the Minkowski sum of the roots of $\Phi$).
The permutohedron and the Coxeter complex are basically the same thing: precisely, the Coxeter complex is the dual of the permutohedron (the dual of a simple polytope is a simplicial polytope). See for instance the article "Coxeter-associahedra" of Reiner and Ziegler mentioned above for a quick review of these facts.
This polytopal construction gives a rather concrete model for the Coxeter complex in all the finite types. You can work out the combinatorics of the Type D case specifically from this construction, but there are also probably places where it is spelled out already.