If $k$ has characteristic zero, then $H^1(k,H)$ is finite (Borel-Serre: https://mathscinet.ams.org/mathscinet-getitem?mr=181643) and the map $G(k)/H(k) \rightarrow (G/H)(k)$ has open image (can also be proved by the implicit function theorem). Moreover, a Baire category argument shownshows that this map is a homeomorphism onto the image. In positive characteristic, there is an old paper by Bernstein Zelevinsky (https://mathscinet.ams.org/mathscinet-getitem?mr=425030; see the appendix) which says (I think) that the map is a homeo onto the image, and that the image is closed.