Two things worth mentioning.
First, is that any value of $\alpha$ related via the moebius transformation,
$$ \alpha = \frac{a+b\varphi}{c+d\varphi} \quad \textrm{for integers} \;\;a,b,c,d \;\; \textrm{where} \; |ad-bc|=1.$$
will also be optimal.
And secondly, $\alpha = 1+\sqrt{2} $ turns out to be the next most badly approximable number -- and therefore the next most optimal value for the construction of a low discrepancy sequence.
Springborn as well as Spalding give number theoretic reasons why this is the second most badly approximable number, and also why $\alpha = \frac{1}{10} (9+\sqrt{221}$ is the third-most badly approximable number.
Interestingly the continued fraction for these three values are:
$$ \varphi = 1+\frac{1}{1+\frac{1}{1+\frac{1}{1+...}}} = [1,1,1,1,...]$$
$$ 1+\sqrt{2} = 2+\frac{1}{2+\frac{1}{2+\frac{1}{2+...}}} = [2,2,2,2,2,2] $$
$$ \frac{1}{10}(9+\sqrt{221}) = 2+\frac{1}{2+\frac{1}{1+\frac{1}{1+...}}} = [2,2,1,1,2,2,1,1,2,2,1,1,..] $$
Part 3. Kronecker low discrepancy sequences in higher dimensions
For $d=2$, $ \phi_2 = 1.3247179572... $, which is often called the plastic constant or silver ratio, and has some beautiful properties. This value was conjectured to most likely be the optimal value for a related two-dimensional problem [Hensley, 2002]. Jacob Rus has posted a beautiful interactive/dynamic visualization of this 2-dimensional low discrepancy sequence, which can be found here.