Let $f:\mathbb{D}=\{z\in\mathbb{C}\mid |z|<1\}\rightarrow\mathbb{C}$ be a local diffeomorphism (i.e. an immersion) from an open disk in the plane to the plane.
The only situation I can image where $f$ is not injective is that $f$ sends $\mathbb{D}$ to a "self-overlapping'' region, in which case $f$ can not have continuous injective boundary values. But it seems non-trivial to proof that such boundary values guarantee injectivity:
Question. Assume that $f$ extends to a continuous map $\overline{\mathbb{D}}\rightarrow\mathbb{C}$ such that the boundary values $f|_{\partial\mathbb{D}}$ is injective and continuous, so that (by Jordan Curve Theorem) it maps $\partial\mathbb{D}$ homeomorphically to a Jordan curve which is the boundary of a simply connected domain $\Omega\subset\mathbb{C}$. Then it is true that $f$ is a homeomorphism from $\mathbb{D}$ to $\Omega$?
Essentially we can reduce the problem to the case where $f|_{\partial\mathbb{D}}$ maps $\partial\mathbb{D}$ identically to $\partial\mathbb{D}\subset\mathbb{C}$ and ask:
Question'. If $f:\overline{\mathbb{D}}\rightarrow\mathbb{C}$ is a continuous map such that $f|_{\partial\mathbb{D}}$ is the identity and $f|_{\mathbb{D}}$ is a local homeomorphism, then is $f$ always injective?