$\DeclareMathOperator{\Noo}{\mathbf{No}}$When seen as a big ordered field, $\Noo$ hasn't much to offer in terms of constants besides real numbers; indeed every other surreal can be sent to pretty much every other surreal by an automorphism preserving the reals. They also lack of interesting geometric/analytic constants simply because there are no established "geometric and analytic theories" of surreals.
However, because of the profusion of inter-related notions that can be defined on surreals, the study of $\Noo$ is actually laden with encounters of specific surreals. In fact I would say they mainly go unnoticed as "constants" because they usually come in proper classes.
Here are a few examples. In each of them, the simplicity relation plays a role as it allows us to chose simplest surreals satisfying given conditions:
-First, there are the simplest in any non empty final segment of $\Noo$, but those are just ordinals.
-Then there are constants that can be defined using sign sequences with nice properties. For instance simplest surreals $x$ such that given a surreal / strictly positive surreal $a$, $a \cdot x= x$ or $a \star x= x$ where $\cdot $ is the concatenation of sign sequences and $\star$ is the "ordinal-like" product of sign sequences. (though those examples will be real numbers or ordinals if $a$ is)
-Then there are singular subclasses of $\Noo$ useful to describe various asymptotic order relations, for instance the $\omega$-map [1], and the corresponding constants, ($\omega^{\frac{1}{\omega}}$ and $\omega^{\frac{\varepsilon_0}{\omega^{\omega}}}$ for instance).
-Fixed points for the corresponding maps when they have (for instance generalized $\varepsilon$-numbers, or the fixed point of $x \mapsto \omega^{-x}$[1])
-For well-behaved functions (such that they preserve o-minimality of the structure for instance), one can look at their fixed points if they have some.
-Surreals corresponding to given logarithmic-exponential asymptotic classes by the correspondance of Berarducci and Mantova, and their formal derivatives (see this paper).
-Infinite irreducible or prime Conway integers (for instance the surreal $1 + \sum \limits_{n \in \mathbb{N}^{>0}} \omega^{-\frac{1}{n}}$$1 + \sum \limits_{n \in \mathbb{N}^{>0}} \omega^{\frac{1}{n}}$, see here and here).
...
I should add that many of the mentioned constants are mysterious in that it may not be clear what their sign sequence or Conway normal form may be, what their exponential is, what asymptotic growth they may represent, and to what classes they belong...
[1] Harry Gonshor, An Introduction to the Theory of Surreal Numbers