The geodesics are straight lines, in geodesic normal coordinates, just when the associated projective connection is flat. See Kobayashi and Nagano, On projective connections, Journal of Mathematics and Mechanics, vol. 13, no. 2, 1964. I am not sure that I have seen a precise description of this condition in terms ofIf an affine connection is projectively flat, then the curvatureWeyl and Cotton tensors vanish, although there must be oneas these are projective connection invariants. (I mistakenly thought it wasIn dimensions 3 or higher, these conditions force the vanishingaffine connection to be that of the Weyl tensora constant curvature Riemannian metric. Indeed, butBeltrami proved that describes conformal, not projective, flatnessa projectively flat affine connection is locally that of a constant curvature Riemannian metric.)