For elementary courses, say up to first year undergraduate or so, Khan Academy has a wide range of courses on maths (some of which are listed under computer science or physics).
For graduate courses, several answers have mentioned MSRI and/or the Hausdorff institute but the Fields Institute video archive deserves a mention as well. The archive does no go back very far, but there are some excellent courses at various levels. (Search for the word "course" on the linked page).