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Jun 4, 2010 at 18:03 comment added Tim van Beek That's tricky! Allow some handwaving: If the potential goes to $\infty$ that means particles are confined to a bounded region (the probability to find them outside is very low/ can be made arbitrarily low). In a bounded region in classical physics there can be different locations which minimize the potential energy, but in quantum mechanics the ground state describes the probability to find it in any of those -> therefore it is unique in QM. But note that you can get degenerate ground states by dropping the other assumption on V ($V \in L^2_{loc}$).
Jun 4, 2010 at 17:02 comment added Jamie Vicary Do you have any insight into what role unboundedness of the potential plays? I mean physically, rather than mathematically?
Jun 4, 2010 at 15:41 vote accept Onkar
Jun 4, 2010 at 15:42
Jun 4, 2010 at 13:19 history edited Tim van Beek CC BY-SA 2.5
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Jun 4, 2010 at 13:09 history answered Tim van Beek CC BY-SA 2.5