Here is a counter-example: let $A=(1,0,0,0,0,1)$, $B=(1,1,1,0,0,0)$, $C=(0,0,1,1,0,0)$ and $D=(0,0,0,1,1,1)$. Take $Y=\{A,B,C,D\}$. Then:
$PE=\{A,B,C,D\}$, so that $conv(PE)=conv(Z)$$conv(PE)=Z$.
The vector $(.5,0,.5,.5,0,.5)$ is in $conv(PE)=conv(Z)$$conv(PE)=Z$, but it is not in $E$ since $(.5,.5,.5,.5,.5,.5)$ is also in $Z$.
(The second or the fourth coordinate can be deleted in the example, to get an example with only five coordinates. I am not sure whether that is smallest possible).