The labeling gives a piecewise linear map from $S^n$ to a simplex $\Delta$ with $n$$n+1$ vertices, where label $k$ means the point is sent to vertex $v_k$, and we extend linearly on simplices. The map must have degree $0$ because $\Delta$ is contractible. The degree can be computed from the preimage of any point in the interior of $\Delta$, and it is the difference between the number of positive simplices and the number of negative simplices.