Yes. The character table of SL(2,q) is knownis known. If q is odd, the sum of the dimensions of the irreducible representations of SL(2,q) is q2+q. If q is even, this sum is q2. In either case, this is bigger than the dimension of $\mathbb{C}\{X\}$, so there must exist irreps not in $\mathbb{C}\{X\}$.