Concerning your first question, I think a good place to learn about it is Markus Banagl's book "Topological invariants of stratified spaces" (chapter 6) or have a look at Paul Siegel's paper "$KO$-homology at odd primes" Amer. J. Math. 105 (1983), 1067-1105 (in particular the appendix where Sullivan's approach is explained).
In Siegel's paper you have a bordism theory $\Omega^{Witt}_*(-)$ build from cobordisms of some singular spaces called Witt spaces. Such spaces carry A Witt space $X$ carries rational homology L-classes and this bordism theory when tensored by $\mathbb{Z}[1/2]$ is naturally isomorphic to $ko_*(-)\otimes \mathbb{Z}[1/2]$$l_i\in H_{dim(X)-4i}(X,\mathbb{Q})$.
Thus for any Witt space in particular for smooth manifolds you have a fundamental class in Witt bordism, when tensored over the rational you get Goresky-McPherson L This homology $L$-classes (obtained thanks to intersection cohomology)were defined by Goresky and thusMcPherson in this singular context extending the smooth case "ordinary" Lhomology $L$-classes. Then use the natural isomorphism between this bordism theory and of a manifold $ko$ at odd-primes$M$ which are poincaré dual to get your formula.Hirzebruch $L$-classes $L_i\in H^{4i}(M,\mathbb{Q})$: $$l_i(M)=L_i(M)\cap [M]$$
In Witt bordism any Witt space has a fundamental class $[X]\in \Omega^{Witt}_{dim(X)}(X)$ represented by $id:X\rightarrow X$.
Moreover we have a natural transformation $$\Phi:\Omega^{Witt}_k(X)\rightarrow \oplus_{i} H_{k-4i}(X,\mathbb{Q})$$such that for a Witt space we have $\Phi([X])=l_0+l_1+\ldots$, for a manifold we get that $\Phi([M])=L(M)\cap [M]$.
And this bordism theory when tensored by $\mathbb{Z}[1/2]$ is naturally isomorphic to $ko_*(-)\otimes \mathbb{Z}[1/2]$. Siegel used Sullivan's construction of $ko_*(-)\otimes \mathbb{Z}[1/2]$ to get a natural transformation $$\mu: \Omega^{Witt}_*(-)\rightarrow ko_*(-)\otimes \mathbb{Z}[1/2].$$ such that $\mu([M])=\Delta_M.$
Concerning your second question you can have a look at theorem 11.1 "Multiplicativity of the L-theory fundamental class" of this paper: "The L-homology fundamental class for IP-spaces and the stratified Novikov conjecture" by Markus Banagl, Gerd Laures and Jim McClure (available on Banagl's homepage).