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Mar 14, 2015 at 12:39 comment added Jim Humphreys The book by Thomas Hawkins is certainly the most comprehensive scholarly history, but for a further account of Killing's influence on the classification you might also try a less formal article by the late A.J. Coleman (which has a provocative title): ams.org/mathscinet-getitem?mr=1007036
Mar 14, 2015 at 9:18 comment added Robert Bryant It's also true that Killing thought that he had found two exceptional root systems of rank $4$. It was Cartan who pointed out that these two were actually isomorphic, bringing the number of exceptional root systems down to $5$. It is amusing to think that $\mathrm{G}_2$ should have been discovered as the symmetry group of the octonions, which had been known for 40 years by the time of Killing's work, but it would be another 20 years after his work that this connection would be made, again by Cartan.
Mar 14, 2015 at 7:29 comment added asv Thanks, it is very interesting and sounds like a final answer to my question.
Mar 14, 2015 at 7:15 comment added user74230 They were first discovered by Killing in the process of establishing the classification for semisimple complex Lie algebras. This is discussed in Chapter 5 Hawkins' book "Emergence of the theory of Lie groups..." (Killing was very surprised to discover G$_2$, etc., and initially had ruled out some such things from existence due to computational error; Killing built $\mathfrak{g}_2$ and convinced himself of the existence of the other exceptional types but didn't complete the existence proof beyond finding what their root systems would have to be, to say it in modern terms that he didn't have).
Mar 14, 2015 at 6:34 history asked asv CC BY-SA 3.0