I have no comment on your methods, and I know very little about this, but that case of Pillai's conjecture appears to have been solved in the 80's by Stroeker and Tijdeman [Edit: see below]. Here's a paper by Bennett from 2001 that shows more: http://www.math.ubc.ca/~bennett/B-CJM-Pillai.pdfBennett, Michael A., On some exponential equations of S. S. Pillai, Can. J. Math. 53, No. 5, 897–922 (2001). ZBL0984.11014. PDF. In particular, the number of solutions is at most 2 for each fixed $r$. More generally, Bennett shows that for fixed integers $a\geq2$, $b\geq2$, and $r\neq0$, there are at most 2 solutions $(m,n)$ to the equation $a^m=b^n+r$. The more general form of Pillai's conjecture allows $a$ and $b$ to vary and appears to still be unsolved.
Edit: What Stroeker and Tijdeman actually did was sharpen the result by showing that except when $r$ is in $\{-1,5,13\}$, your equation has at most one solution, and that in the exceptional cases it has two. The finiteness of the set of solutions $(m,n)$ to the equation $a^m=b^n+r$ had long been known, and Pallai himself gave some quantitative results on this using Siegel's Theorem. For finiteness alone without quantification, Bennett cites this 1918 Polya paper1918 Pólya paper. My source for all of this is Bennett's paper.