Supposedly Stefan Bergman attended a course on orthogonal functions while an undergraduate, and misunderstood what he was hearing, believing that the functions were supposed to be analytic. This led him to the Bergman kernel and Hilbert spaces of analytic functions, which has developed into a whole field of study at the junction of complex analysis and operator theory, and also with important ramifications in the more geometric parts of SCV. If the story is true, this was certainly an extremely fruitful mistake!