Here is one of my favorites. If you consider a singular node of an algebraic curve locally it looks like the curves $xy=0$ in $\mathbb{C}^2$, or $x^2+y^2=0$. This consists of two smooth arcs intersecting to each other transversally (reducible in particular).
Now, one step further, if we consider a cusp which is analytically equivalent to the origin in the curve $y^2+x^3=0$ in $\mathbb{C}^2$, it is locally irreducible. However, here comes the interesting point, if we intersect the singularity with a small ball $$[(x,y)\in \mathbb C^2:\ |x|^2+|y|^2=\epsilon]\cong S^3$$ what we've got is that such an intersection is $$(ae^{2i\theta},a^{3/2}e^{3i\theta})\subset S^1\times S^1\subset S^3$$ which is contained in a torus winding two times in one direction in the torus and three times in the other direction, in other words, we have an trefoil knot. alt text http://upload.wikimedia.org/wikipedia/commons/d/df/TrefoilKnot-01.png
Now in the case of surfaces, all these facts give rise to an amazing relation between topology and algebraic geometry. The underlaying space topological space in $\mathbb C^4$ of $$x^2+y^2+z^2+w^3=0$$ is a manifold!! (note it is singular at the origin in the context of AG!). As far as I know, if one intersects a small ball with the singularity, as I did above, one gets a topological sphere whose differential structure is NOT the standard one. Even more, considering in $\mathbb C^5$ the following hypersurface $$x^2+y^2+z^2+w^3+t^{6k-1}=0$$ and carrying out the intersection with a small sphere around the origin, for $k=1,2,\ldots 28$ one may get all the 28 possible exotic differential structures on the 7-sphere that Milnor found.