In searching through the Riemann Nachlass in Gottingen (including those
folders not listed as connected with \zeta(s)) $\zeta(s)) $ there is no
evidence -- at least that has been saved -- that Riemann computed
anything more than the first few zeros (I think up to ordinate about 80).
The method he used was the expansion that is now called the Riemann-Siegel
formula. I did not see any use, e.g., of an approach based on
Euler-Maclaurin. The limited accuracy Riemann obtained reflects that of
the error term in the R-S formula.