I'm not entirely sure what exactly your left side means, but I'll try for the closest fit. If $M$ is compact oriented and Riemannian, the Hodge theorem gives that the space of $C^\infty$ $i$-forms decomposes as an orthogonal direct sum $(\text{harmonic forms})\oplus im(d)\oplus im(d^*)$$(\text{harmonic forms})\oplus im(d)\oplus im(d^\ast)$. This will imply that if you consider the $d+d^*$$d+d^\ast$ as a map from the space of even degree forms to odd degree forms, then the index is exactly the Euler characteristic on the right side of your equation. I don't know about an online ref. but lots of books (Griffiths-Harris, de Rham, Warner, Wells...) give a proof of the Hodge theorem.
Added... In more detail $$index(d+d^\ast) = \dim \ker (d+d^\ast)|_{\text{even forms}}-\dim im (d+d^\ast)^\perp |_{\text{odd forms}}$$ The above kernel is the space of even harmonic forms, which can be identified with $H^{even}(M)$ by the Hodge theorem. The second space can be identified with $H^{odd}(M)$ for similar reasons.