Is it not zero whenever $n \geq 2$? Let $A$ be a $n \times n$ permutation matrix with determinant $-1$ (which requires $n \geq 2$). Then the uniform distribution of a random $n \times n$ $(0,1)$-matrix $X$ is the same as the distribution of $XA$. The permanent is multiplicative, hence Per$(AX)=$Per$(A)$Per$(X)=-$Per$(X)$. Hence the probability of Per$(X)=x$ is the same as the probability of Per$(X)=-x$.

Is it not zero whenever $n \geq 2$? Let $A$ be a $n \times n$ permutation matrix with determinant $-1$ (which requires $n \geq 2$). Then the uniform distribution of a random $n \times n$ $(0,1)$-matrix $X$ is the same as the distribution of $AX$. The determinant is multiplicative, hence Det$(AX)=$Det$(A)$Det$(X)=-$Det$(X)$. Hence the probability of Det$(X)=x$ is the same as the probability of Det$(X)=-x$.