[Edit: I have added some details, and a more explicit example by Milnor.]
We will make fundamental use of the following fact: if $M$ and $N$ are two $h$-cobordant, closed, smooth (respectively, topological) manifolds of dimension greater than 3, then $M\times\RR$ is diffeomorphic (respectively, homeomorphic) to $N\times\RR$. [Aside: A similar statement holds for topological manifolds; simply replace diffeomorphism with homeomorphism.] Here are a couple of quick references for this fact, both making use of the $s$-cobordism theorem:
[AsideFurther aside: Incidentally, the converse also holds — although we will not make use of it. In another mathoverflow question, Igor Belegradek remarks in his answer and the ensuing comments that if $M\times\RR$ is homeomorphic to $N\times\RR$, then $M$ and $N$ are $h$-cobordant.]
So it suffices to find closed smooth manifolds $M$ and $N$ which are $h$-cobordant, yet not homeomorphic. As required by the question, we also want $M$ to be null-cobordant; then $N$ will be null-cobordant as well. As a minor bonus, in all the examples presented below,since $M$ and $N$ are smooth manifolds which are smoothly $h$-cobordant, so $M\times\RR$ is actually diffeomorphic to $N\times\RR$.
One such example is given by Farrel and Hsiang in their article "$H$-cobordant manifolds are not necessarily homeomorphic". There, the manifold $M$ is a product $M=L\times\TT^n$, where $L$ is any 3-dimensional lens space such that $\pi_1(L)\simeq\ZZ/p^2$ for some prime $p$, and $\TT^n=(S^1)^{\times n}$ is a torus of dimension $n\geq 3$. Note that $M$ is null-cobordant since the torus $\TT^n$ is null-cobordant. Unfortunately, the methods used by Farrel and Hsiang do not explicitly describeyield an explicit description of the manifold $N$.
I will briefly describe how to conclude from Milnor's article that the preceding $M$ and $N$ above actually meet our requirements. In section 2, Milnor sketches a proof that $M$ and $N$ are $h$-cobordant. At the end of section 4, in the proof of corollary 2, he uses the fact that $L(7,1)$ and $L(7,2)$ have distinct Reidemeister torsion to concludetorsions, and concludes that $M$ and $N$ also have distinct Reidemeister torsion themselvestorsions, and thus are not diffeomorphic. But more is true: since the Reidemeister torsions of $M$ and $N$ differ, $M$ and $N$ are not homeomorphic. This follows from the topological invariance (i.e. invariance under homeomorphisms) of Reidemeister torsion, which is itself a simple consequence of the topological invariance of Whitehead torsion — proved by Chapman after the publication of Milnor's article.