Main question. Does there exist a smooth projective morphism $X\to$ Spec $\mathbf Z$ of relative dimension two such that the canonical sheaf $\omega_{X_{\mathbf Q}}$ of the generic fibre $X_{\mathbf Q}$ is ample?
Replacing "relative dimension two" by "relative dimension one", the answer is negative by a theorem of Abrashkin-Fontaine. I highly suspect the answer to be negative in this case too. Unfortunately, it is not known yet though as confirmed by Sándor.
Question 2. Does there exist a number field $K$ such that there are infinitely many $K$-isomorphism classes of smooth projective geometrically connected surfaces over $K$ with ample canonical sheaf and a smooth projective model over $O_K$?
The answer is positive if we replace "surfaces" by "curves". And as Will points out the answer is positive in the higher-dimensional case.
My main question is part of the arithmetic Shafarevich conjecture. As the terminology suggests, this conjecture is the arithmetic analogue of a conjecture for geometric objects. The latter (geometric) conjecture has been resolved by Arakelov, Bedulev, Kovács, Lieblich, Möller, Parshin, Viehweg, Zuo, et al. (Edit: Please see the references in Sándor's answer.) Its arithmetic analogue remains widely open for relative dimension $\geq 2$ to my knowledge, and was resolved in 1983 by Faltings for relative dimension 1.
With my second question I would like to assure myself of the non-triviality of a higher-dimensional arithmetic Shafarevich conjecture. It turns out to be trivial.
Let me state the results (due to the before-mentioned) in algebraic geometry relevant to this question. The base field is an algebraically closed field $k$ of characteristic zero.
Theorem 1. (Higher-dimensional geometric analogue of main question) There are no smooth projective (strongly?) non-isotrivial morphisms $X\to \mathbf P^1_k$ such that the canonical sheaf of the generic fibre of $X\to \mathbf P^1_k$ is ample.
Theorem 2. ("Folklore?" Higher-dimensional geometric analogue of second question) Fix $d\geq 0$. There exists a smooth projective connected curve $C$ such that there are infinitely many isomorphism classes of (strongly?) non-isotrivial smooth projective morphisms $X\to C$ of relative dimension $d$ whose generic fibre has ample canonical sheaf.
Now, Theorem 2 is one of the reasons that the following grand finiteness theorem is difficult.
Theorem 3. Let $C$ be a smooth projective connected curve and let $h$ be a polynomial. Then, there are only finitely many isomorphism classes of smooth projective (strongly?) non-isotrivial morphisms $X\to C$ whose generic fibre is canonically polarized with Hilbert polynomial $h$.
Let me note that I am considering function fields over a field of characteristic zero to be analogous to Spec $\mathbf O_K$. I know some of you prefer function fields over finite fields, but regarding these questions the analogy also "works" to a certain extent.
I might have stated Theorems 1-3 slightly incorrectly. In this case I apologize. (Also, I didn't state Theorem 3 in its full generality. The base curve doesn't need to be compact for instance.) Maybe, I should have only considered deformation types of families over $C$ in the statements.
Finally, let me point out some related MO questions:
What can be the dimension of a pointless smooth proper Z-scheme?What can be the dimension of a pointless smooth proper Z-scheme?