For a simple Lie group $G$ and representation $\rho:G\to GL(n,\mathbb C)$ with infinitesimal representation $\rho':\mathfrak g \to \mathfrak g\mathfrak l(n,\mathbb C)$ we have $Trace(\rho'(X).\rho'(Y)) = j_{\rho} B(X,Y)$ where $B$ is the Cartan-Killing form, for a constant $j_{\rho}$, which is called the Dynkin index (up to a possible factor due to normalizationnormalization; if done right, $j_\rho$ is always an integer). This This is, because the quadratic bi-invariantinvariant functions form a 1-dim. vector space in this case.
So it is already isometric up to a conformal factor. Multiply
Edit: Multiplying it away is not possible (Thanks, Robert). You
You do this for each simple part of the Lie algebra, stacking matrices, and get it for semisimple compact Lie groups. Then you play with the center.