Let $(S_n)_{n=1}^{\infty}$ be a standard random walk with $S_n = \sum_{i=1}^n X_i$ and $\mathbb{P}(X_i = \pm 1) = \frac{1}{2}$. Let $\alpha \in \mathbb{R}$ be some constant. I would like to know the value of
$$\mathcal{P}(\alpha) := \mathbb{P}\left(\exists \ n \in \mathbb{N}: S_n > \alpha n\right)$$
In other words, I am interested in the probability that a random walk $(S_n)_{n=1}^{\infty}$ crosses the straight line through the origin with slope $\alpha$.
Since the standard random walk is recurrent, it follows that $\mathcal{P}(\alpha) = 1$ for $\alpha \leq 0$, while obviously $\mathcal{P}(\alpha) = 0$ for $\alpha \geq 1$. Hence the non-trivial part and the part I am interested in is the region $\alpha \in (0,1)$. For this region we know that $\mathbb{P}(S_1 > \alpha) = \frac{1}{2}$, hence $\mathcal{P}(\alpha) \geq \frac{1}{2}$, but finding an exact value seems difficult.
Note: One way to explicitly calculate $\mathcal{P}(0)$ is by
$$\mathcal{P}(0) = \sum_{n=1}^{\infty} \frac{C_n}{2^{2n-1}} = 1$$
where $C_n$ is the $n$-th Catalan number, as was pointed out on e.g. http://oeis.org/A000108 by Geoffrey Critzer. For general $\alpha$ however such a summation does not seem to give a nice expression, since the coefficients are uglier and the exponents of $2$ depend on $\alpha$ (for $\alpha = 0$ one gets exponents $2n - 1$, but for irrational $\alpha$ this exponent becomes something ugly). But finding a closed form for these coefficients for general $\alpha$ might also help solve this problem.
Edit: As it may be too much to ask for a nice formula for $\mathcal{P}(\alpha)$, I would also be very happy if someone could provide (good) bounds on or approximations of the value of $\mathcal{P}(\alpha)$. For example: Does $\mathcal{P}(\alpha)$ decrease linearly in $\alpha$? Any insight is very much appreciated!

