I am an optical engineer, so please forgive any ignorance my questions betoken. I am interested in whether one can tear down the manifold of a finite dimensional Lie group,
Example 1: Take the additive group $\left(\mathbb{R},\cdot +\right)$, it is its own Lie algebra. As the lie algebra I denote it $\mathbf{g}$ and the Lie group $G$ - arising from the two topologies are isomorphic, their topologies are homoemorphic.
Example 2: I believe, if the following is right, that connected centreless Lie group must also "behave itself" in the above way, i.e. if you can give it a topology to make it into a connected Lie group in many different ways, the Lie groups so built must all have the same Lie algebra, fundamental group and connected components. For suppose two different topologies / manifolds make it into connected Lie groups $G$ and $G^\prime$; here we also allow for there being different Lie algebras $\mathbf{g}$ and $\mathbf{g}^\prime$. We think of smooth paths
$\sigma\left(\tau\right)=\exp\left(\tau X\right) \in G;\; X \in \mathbf{g}$ and $\sigma^\prime\left(\tau\right)=\exp^\prime\left(\tau X^\prime\right) \in G^\prime; \; X \in \mathbf{g}^\prime$. As for Example 1, there are two different exponential maps $\exp$ and $\exp^\prime$. In the centreless case, the adjoint $G$ and $G^\prime$ are locally isomorphic to (have the same Lie algebras as) the groups of big Ad matrices acting through the adjoint group representations on their respective Lie algebras. Now, even though $\sigma^\prime$ might be totally disconnected in $G$'s toplogy and contrawise, $\sigma, \sigma^\prime$ induce smooth paths $\exp_M\left({\rm ad}_X\right) \in \left(\mathbf{g}\right)$, $\exp_M\left({\rm ad}_X^\prime\right)\in gl\left(\mathbf{g}^\prime\right)$ through their respective adjoint representations and here $\exp_M$ is now the same, in the sense its being the restriction from the continuous one defined on $gl\left(N, K\right)$), continuous matrix exponential. Here $N$ is the Lie group dimension (if we allow for it to be different for the two topologies, we assume it is the bigger number) and $K = \mathbb{R}, \mathbb{C}$, as appropriate. So now we have potentially different linear Lie subgroups $G_L$ and $G^\prime_L$ of $gl\left(N, K\right)$, each locally isomorphic to $G$ and $G^\prime$, respectively. So we now find the universal covers of the four groups $G$, with its locally isomorphic $G_L$ and $G^\prime_L$ with its locally isomorphic $G^\prime_L$, we have linear $\hat{G} \cong \hat{G_L}$, $\hat{G}^\prime \cong \hat{G^\prime_L}$; the covers are central extensions with the discrete fundamental groups as kernel of the projections back tooriginal groups. With $G$ and $G^\prime$ being the same as sets, if the universal covers in the two topologies are not the same, one must be a cover of the other. But this would imply that they both have isomorphic Lie algebras. So the topologies can't be different (otherwise one couldn't be a universal cover). Hence the two universal coversare isomorphic as Lie groups. Modding out the centres, i.e. the fundamental group to get back to centreless groups, we show that an automorphism of G that preseres Liealgebras and fundamental groups takes it to $G^\prime$.
Example 3: I don't believe example 2 is affected by the presence of a discrete centre. Thus groups with discrete centre only can only be given a Lie group structure in essentially one way.
Example 4: Special cases of example 3 would be any connected group with semisimple Lie group.
Example 5: I believe I can get a vector generalisation of the technique in Example 1 to work for connected Abelian Lie groups.
The above leaves out animals like the Heisenberg group, other nilpotent beasts, solvable groups as could-be problem children.

