When I was a freshman, I was asked to prove the fundamental theorem of algebra on the final exam for multivariable calculus (I'm completely serious: I think the problem just stated the FTA and asked us to give a proof.)
I didn't succeed, but what I was supposed to do (I think) was apply the Gauss-Bonnet Theorem. One version of this proof appeared recently:
Yet another application of the Gauss-Bonnet Theorem for the sphere J. M. Almira and A. Romero Source: Bull. Belg. Math. Soc. Simon Stevin Volume 14, Number 2 (2007), 341-342.
In this paper the authors use the version of Gauss-Bonnet that relates the Gaussian curvature to the Euler characteristic.
I guess there's another version of this in which one instead uses the version of Gauss-Bonnet saying that the Euler characteristic is the same as the sum of the indices of any vector field (sometimes this theorem is attributed to Poincaré).
The vector field to consider is just $z \mapsto 1/p(z)$, which is well-defined for non-constant polynomials $p(z) = z^n + a_{n-1} z^{n-1} + \cdots + a_0$ without roots, because it vanishes at infinity. The index at infinity for this vector field is the degree of $p$. So if $p$ is a non-constant polynomial without roots, we'd need to have deg$(p) = \chi(S^2) = 2$. Since degree 2 polynomials have roots (the quadratic formula!), this completes the proof.
