The second problem (with where real scalar variables and the comparison relation are also allowed) is equivalent to the first problem. Here is a standard argument showing this:
- A complex scalar variable z can be restricted to real values by requiring $\exists z_1\exists z_2.\ z=z_1\bar{z}_1-z_2\bar{z}_2$, where z1 and z2 are fresh complex scalar variables.z=\bar{z}$.
- The comparison x≤y can be replaced by $\exists z.\ x+z\bar{z}=y$, where z is a fresh complex scalar variable.
Back to the original question, the following paper may be related (or even answer your question) but I do not have enough knowledge to understand the content completely. Mihai Putinar: Undecidability in a Free *-Algebra, preprint, April 2007, http://www.ima.umn.edu/preprints/apr2007/2165.pdf.

