Ask someone to lay out the 52 cards in a deck, face up, in 4 rows of 13 cards each, in any order the person wants. Then you can always pick 13 cards, one from each column, in such a way as to get exactly one card of each denomination (that is, one ace, one deuce, ..., one king).
As a trick, it's not up there with sawing a woman in half, but its explanation does require Hall's Marriage Theorem.
