If $G$ acts freely and cellularly on a CW-complex, permuting the cells, then the stabilizer of a cell must be finite (and therefore trivial, as pointed out in the question).
This can be shown by induction on the dimension, the case of 0-cells being trivial. If $\sigma$ is an $n$-cell, with $n\geq 1$, let $H$ be the stabilizer of $\sigma$. Then $H$ permutes the set of cells with dimension less than $n$ in the closure of $\sigma$. But there are only finitely many such cells, and inductively each has finite (indeed, trivial) stabilizer. Thus $H$ is finite.

