For convex figure $\Sigma$ in $\mathbb S^2$, the isoperimetrical inequality should look like $$\left(\frac{\mathop{\rm perim}\Sigma}{2\cdot\pi}\right)^2+\left(1-\frac{\mathop{\rm area}\Sigma}{2\cdot\pi}\right)^2\ge 1.$$
If $\Sigma$ and $\Sigma'$ are the intersections of $\mathbb S^2$ with your cones then by Crofton formula we get $$\frac{\mathop{\rm perim}\Sigma}{2\cdot\pi}+\frac{\mathop{\rm area}\Sigma'}{2\cdot\pi}=1$$ Hence te result.
P.S. The extreme values should be for round cone and positive octant, but I do not see a proof in higher dimensions.

