The only example I know of a positive map which is not completely positive is the transpose map on $M_n(\mathbb{C})$. Of course, one can come up with minor perturbations of this (compose it with, or add it to, a completely positive map, etc). Are there other known examples?
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In Theorem 4.6 of their paper http://www.univie.ac.at/nuhag-php/bibtex/open_files/deha85_CanniereHaagerup.pdf de Canni`ere and Haagerup construct an explicit sequence of finitely supported functions on the free group $\mathbb{F}_N$ ($N\geq 2$), defining positive multipliers of the reduced C*-algebra $C^*_r(\mathbb{F}_N)$, and such that the corresponding sequence of multipliers converges strongly to the identity of $C^*_r(\mathbb{F}_N)$. As $C^*_r(\mathbb{F}_N)$ is non-nuclear, it does not have the completely positive approximation property, so only finitely many of these multipliers are completely positive. |
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I know nothing but a quick google search gives http://www.quantiki.org/wiki/Separability_criteria where 2 other examples are given. Maybe somebody who knows more can flesh it out so I made this CW. |
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First, let me recall some definitions to make sure I understand (at least the matrix version of) the question correctly. All of what I say below is based on Chapter 3 of the delightful book Positive Definite Matrices by R. Bhatia. Let $\mathbb{M}_n$ denote the space of $n \times n$ complex matrices over $\mathbb{C}$, and let $\mathbb{M}_k(\mathbb{M}_n)$ denote the set of $k \times k$ block matrices, having elements of $\mathbb{M}_n$ as its blocks. I'll just speak of positive and completely positive maps, and not restrict to linear maps (yet). Consider the map $\Phi_k: \mathbb{M}_k(\mathbb{M}_n) \to \mathbb{M}_k(\mathbb{M}_p)$, is induced by a positive map $\Phi: \mathbb{M}_n \to \mathbb{M}_p$, so that in particular for a $k\times k$ block matrix $A$, we have \begin{equation*} \Phi_k(A) := [\Phi(A_{ij})]. \end{equation*} If $\Phi_k$ is a positive map for all $k=1,2,\ldots,$, then $\Phi$ is called a completely positive (CP) map. Notice that $k=1$ coincides with "ordinary" positive maps. Now, with this definition, it is quick matter to construct maps that are positive but not CP, for example, say the map $X \mapsto X^{-1}$ on positive matrices. Additionally, if you are looking only at positive linear maps and and CP linear maps, then you can appeal to a theorem of Choi and Kraus that says that each CP map $\Phi$ must assume the representation $\Phi(A) = \sum_i V_i^*AV_i$, and you need only find a positive (linear) map that does not assume this representation. Why the above should be true can also be seen from the following deeper observation. Suppose that every positive linear map $\Phi: \mathbb{M}_n \mathbb{M}_p$ could be written as $$\Phi(A) = \sum_i V_i^*AV_i + \sum_j V_j^*A^TV_j,$$ then it would follow that every real polynomial in $n$ variables that takes only nonnegative values is a sum of squares of real polynomials. But this claim was shown to be false by Hilbert. |
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One example other than the transpose is Arveson's example of a non-contractive unital positive map (see Paulsen's book, Example 2.2). Since any unital completely positive map is contractive, Arveson's map cannot be completely positive. The example is like this: let $\mathcal{S}$ be the operator system
This example might not be satisfactory for some operator algebraists because it cannot be extended to an example with a C |
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Here's something neat: Here it is proved, by Sixia Yu, that in the finite-dimensional case, any positive map that isn't completely positive can be written as the difference of two completely positive maps. The paper also considers a necessary and sufficient condition for a positive map to fail complete positivity (also in finite dimensions). This paper apparently provides a mechanism for generating examples answering your question in the finite-dimensional case. |
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A Jordan homomorphism between C*-algebras is always positive, but it is completely positive only if it is a homomorphism. To get some examples, say |
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Continuation of the answer of Benjamin Steinberg; this paper gives a list of such known maps. On the structure of entanglement witnesses and new class of positive indecomposable maps: by Dariusz Chruscinski and Andrzej Kossakowski; http://xxx.imsc.res.in/abs/quant-ph/0606211v1 and the journal version (if you want) is here. It is slightly outdated but gives a good starting point. Not many classes of such maps are known in literature. |
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