You seem to be missing a T on the left when defining the relation $\leq$ on the Lindenbaum algebra, an error which seems to undercut the premise of your question about duals.

Namely, one wants to define that $\phi\leq\psi$ if and only if $T\vdash \phi\leftrightarrow\phi\wedge\psi$. This is the same as $T\vdash\phi\to\psi$.

You need to include the theory $T$ in this definition, since otherwise the relation is not well-defined on your equivalence classes. For example, you won't even be able to prove that $\phi\leq\phi'$ when $\phi$ and $\phi'$ have been already identified by the first part of your definition. Thus, the way you have set things up, the relation $\leq$ will not be well-defined on the equivalence classes you have set up, but using the theory $T$ when defining the order does make things well-defined.

The point of the Lindenbaum algebra is that the objects in the Lindenbaum algebra represent the possible assertions that you can make, having already committed yourself to the theory $T$. These form a Boolean algebra, and the order in that case is simply the usual order arising in any Boolean algebra. It is not a defect that the algebra has only two elements when $T$ is complete, since if you are committed to a complete theory, then every statement is either proved or refuted by the theory, and these are the two kinds of statements you can make. The way I would describe the situation is that the algebra is more interesting when the theory leaves matters unsettled, since the point of the algebra is to understand the nature of what is not yet settled by $T$. I think you can find an account of the Lindenbaum algebra in any of the standard logic texts, but I'd have to double check for a specific reference.

But if we do consider the notion that you have set up, your objects are the Lindenbaum algebra of the underlying language with no theory, but you have a new relation, which is merely a pre-order, arising from the order as defined using theory $T$. Note that different objects $x$ and $y$ in your algebra can obey $x\leq y\leq x$ with $x\neq y$, so this is a pre-order rather than an order. But if we were to quotient by the corresponding equivalence relation, we would get exactly the Lindenbaum algebra arising from the theory $T$, since $\varphi\leq\psi\leq \varphi$ if and only if $\varphi$ and $\psi$ are equivalent in the Lindenbaum algebra of $T$.