I find the following question embarrassing, but I have not been able to either resolve it, or to find a reference.

What is the vertex angle of a regular $n$-simplex?

Background: For a vertex $v$ in a convex polyhedron $P$, the vertex angle at $v$ is the proportion of the volume that $P$ occupies in a small ball around $v$. In symbols, $$\angle v=\lim_{\varepsilon\to 0} \frac{|B(v,\varepsilon)\cap P|}{|B(v,\varepsilon)|}.$$ Up to normalization, this definition agrees with the familiar definition of the angles in the plane, or the solid angle in $3$-space.